I've thought about fitting a sports cat - not just for MOT purposes, but just in case I was pulled for a roadside emissions/safety check.
From what I've read on various forums, a sports cat doesn't always seem to guarantee an emissions test pass but, as with any cat, it must be hot to have a decent chance of passing.
It would appear that with a roadside test they ask you to get the emissions problem sorted within a couple of weeks and retested (at an MOT station, I assume), but they could also issue a fixed penalty at the time of the 'pull'.
For the sake of a few bhp, I think it may be worth having a sports cat fitted to ensure hassle-free motoring - at least as far as emissions are concerned. I'll look into this further next year.
http://www.dft.gov.uk/vosa/publications/businesslinkwebpages/vehicleemissionschecksandstops.htm